##plugins.themes.bootstrap3.article.main##

Acrylonitrile-butadiene-styrene (ABS) is a common waste polymer by-product from industry. Outdated medicines are usually discarded and could be a valuable asset for other applications such as metallic corrosion inhibition. The aims of the present work is to manufacture a recycled ABS polymer doped with outdated lansoprazole medicament as a corrosion protection composite coating. It was applied to mild steel and immersed in chloride solution, and evaluate its possible corrosion protection properties using different electrochemical techniques. The manufactured coating presents good corrosion protection properties showing an 80% efficiency as a function of time of immersion in the aggressive solution.

Downloads

Download data is not yet available.

References

  1. N. Agrawal, D. Campbell, M. Safdi, N. Lukasik, B. Huang, and M. Haber, ¨Superiority of lansoprazole vs. ranitidine in healing non-steroidal anti-inflammatory drug-associated gastric ulcers: results of a double-blind, randomized, multicenter study. NSAID-Associated Gastric Ulcer Study Group¨. Archives of Internal Medicine, Vol.160, 10, pp.1455–1461. 2000.
     Google Scholar
  2. B. D. Mert, M.E. Mert, G. Kardas and B.Yazıcı. ¨Experimental and theoretical investigation of 3-amino-1,2,4-triazole-5-thiol as a corrosion inhibitor for carbon steel in HCl medium¨. Corros. Sci., Vol. 53, pp. 4265–4272, 2011.
     Google Scholar
  3. M Palomar-Pardavé, M. Romero-Romo, ¨H. Herrera-Hernández, M. A. Abreu-Quijano, N. V. Likhanova, J. Uruchurtu and J. M. Juarez-Garcia¨, Influence of the alkyl chain length of 2 amino 5 alkyl 1,3,4 thiadiazole compounds on the corrosion inhibition of steel immersed in sulfuric acid solutions, Corros. Sci., Vol. 54, 1, pp. 231-243, 2012.
     Google Scholar
  4. V. Bustos-Terrones, J. Uruchurtu, J. J. Rochín-Medina, K. Ramírez, J. G. Rangel-Peraza, M. A. Romero-Romo and Y. Bustos-Terrones. ¨Synthesis, characterisation and electrochemical evaluation of a functionalised coating for mild steel corrosion protection¨, Surface Eng., Vol. 35, 4, pp. 360-369, 2019.
     Google Scholar
  5. J. Uruchurtu Chavarin, ¨Electrochemical Investigations of the Activation Mechanism of Aluminum¨, Corrosion. Vol. 47, 6, pp. 472-479, 1991.
     Google Scholar
  6. M. Hernández-Escampa, F. Rodríguez-Acuña, F. Millán-Cruz, P. Rodríguez-Rojas, M. A. Hernández-Gallegos, A. Covelo, C. Menchaca-Campos, and Jorge Uruchurtu, ¨Electrochemical Evaluation of a Recycled Copolymer Coating for Cultural Heritage Conservation Purposes¨ Int. J. Polymer Sci., Vol. 2013, pp.1-9, 2013.
     Google Scholar
  7. V.Bustos, L. Concha, C. Menchaca-Campos, J. Uruchurtu, M. A. Romero, M. Esparza, A. Covelo, M. A. Hernandez and E. Sarmiento, ¨Eco-Friendly Recycled Pharmaceutical Inhibitor/ Waste Particle Containing Hybrid Coatings for Corrosion Protection, Chapter 10, Biobased and Environmental Benign Coatings, Wiley, 2016.
     Google Scholar
  8. J. Uruchurtu-Chavarin and J. M. Malo, “Electrochemical noise as a powerful electrochemical technique for corrosion studies,” Trends in Corrosion Research, Vol. 2, pp. 49–58, 1997.
     Google Scholar
  9. R. Cottis, and S. Turgoose. "Electrochemical impedance and noise, corrosion testing made easy.", Ed. B. C. Syrett, NACE International, Houston, 1999.
     Google Scholar
  10. R. Krache and I. Debbah, “Some mechanical and thermal properties of PC/ABS blends,” Mat. Sciences and Appl., Vol. 2, 5, pp. 404–410, 2010.
     Google Scholar
  11. ASTM D3359 Standard, ¨Test Methods for Rating Adhesion by Tape Test¨. ASTM International, West Conshohocken, PA, 2017.
     Google Scholar
  12. M. Robinson, and J. Horn. ¨Clinical Pharmacology of Proton Pump Inhibitors. What the Practising Physician needs to know¨. Drugs. Vol. 63, pp. 2739-54, 2003.
     Google Scholar
  13. H. J. Flitt and D. P. Schweinsberg. ¨Evaluation of corrosion rate from polarisation curves not exhibiting a Tafel region¨. Corros. Sci. Vol. 47, pp. 3034–3052, 2005.
     Google Scholar
  14. G. Gece. ¨Drugs: A review of promising novel corrosion inhibitor¨. Corros. Sci., Vol. 53, pp. 3873–3898, 2011.
     Google Scholar
  15. N. Vaszilcsina, V. Ordodib and A. Borzaa. ¨Corrosion inhibitors from expired drugs¨, Int. J. of Pharmaceutics. Vol. 431, pp. 241– 244, 2012.
     Google Scholar
  16. J.N Murray and H.P. Hack. ¨Long-term testing of epoxy-coated steel in ASTM seawater using electrochemical impedance spectroscopy¨. Corrosion, Vol. 47, 6, pp. 480-489, 1991.
     Google Scholar
  17. F. Mansfeld, and M. W., Kendig, ¨Determination of the polarization resistance form impedance measurements¨, Werkstoffe und Corrosion, Vol. 34: pp. 397-401, 1983.
     Google Scholar
  18. M. Hernandez, J. Genesca, J. Uruchurtu, F. Galliano and D. Landolt, ¨Effect of an inhibitive pigment zinc-aluminum-phosphate (ZAP) on the corrosion mechanisms of steel in waterborne coatings¨, Prog. in Org. Coatings, Vol. 56, 2-3, pp. 199-206, 2006.
     Google Scholar
  19. E. Ituen, O. Akaranta and A. James. ¨Evaluation of Performance of Corrosion Inhibitors using Adsorption Isotherm Models: An Overview¨. Chem. Sci. Int. J., Vol. 18, 1, pp. 1-34, 2017.
     Google Scholar
  20. M. Y. Díaz-Cardenas, M. G. Valladares-Cisneros, C. Menchaca-Campos, S. Lagunas-Rivera, J. G. Gonzalez-Rodríguez1, J. Uruchurtu-Chavarín, Electrochemical and chemical quantum studies of a natural alkaloid compound: Boldine, as green corrosion behaviour on carbon steel and Copper in sulfuric acid, J. Mater. Environ. Sci., 2019, 10(10), pp. 1011-1024.
     Google Scholar
  21. A. Carmona-Hernandez, E. Vazquez-Velez, J. Uruchurtu-Chavarin, J. G. Gonzalez-Rodriguez and L. Martinez-Gomez, ¨Use of an imidazol synthetized from palm oil as a corrosion inhibitor for a supermartensitic stainless steel in H2S¨, Green Chem. Lett. and Reviews, Vol. 12, 1, pp. 89-99, 2019.
     Google Scholar
  22. M. G. Wyzgoski, “Effects of oven aging on ABS, poly (acrylo- nitrile-butadiene-styrene),” Polymer Eng. and Sci., Vol. 16, 4, pp. 265–269, 1976.
     Google Scholar
  23. C. Monticelli, A. Frignani and G. Trabanelli. ¨Corrosion inhibition of steel in chloride-containing alkaline solutions¨. J. of Appl. Electrochem., Vol. 32, pp. 527–535, 2002.
     Google Scholar
  24. R. Selvaraj, M. Selvaraj and S.V.K. Iyer. ¨Studies on the evaluation of the performance of organic coatings used for the prevention of corrosion of steel rebars in concrete structures¨. Progr. in Org. Coat., Vol. 64, pp. 454–459, 2009.
     Google Scholar
  25. D. Thirumoolan, T. Siva, K. Vetrivel, S. Sathiyanarayanan, K. Anver Bashaa. ¨Corrosion resistant performance of hydrophobic poly(N-vinyl imidazole-co-ethyl methacrylate) coating on mild steel¨. Progr. in Org. Coat., Vol. 89, pp.181–191, 2015.
     Google Scholar
  26. C. López-Meléndez, R.G. Bautista-Margulis, E. M Garcia-Ochoa, H. E. Esparza-Ponce, C. Carreño-Gallardo, C. Gaona-Tiburcio, J. Uruchurtu-Chavarín and A. Martínez-Villafañe, ¨Evaluation of Corrosion Resistance of Thin Films 304 Stainless Steel Deposited by Sputtering¨. Int. J. Electrochem. Sci., Vol. 7, pp. 1149-1159, 2012.
     Google Scholar


Most read articles by the same author(s)