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This study investigates the effect of concentration of different ratio of the leaves extracts Bitter leaf (Vernonia amygdalina) and Banana stem (Musa Acuminata) on corrosion of mild steel in acidic medium using weight loss method at different temperatures (303 K to 323 K) to determine the inhibitory potentials of the extracts. The FTIR and SEM were used to determine the functional groups and morphology of the mild steel respectively during the experiment. The results showed that the inhibition efficiency (IE) increased with an increase in the concentration of the inhibitor (0.1 g/l to 0.5 g/l) but decreased with an increase in temperature (303 K to 323 K) for all the ratios of bitter leaf and banana stem extracts used. The results also showed that the inhibition efficiency increases with an increase in the concentration and shows maximum inhibition efficiency of (80.85%) at optimum concentration (0.5 g/L) The Energy Dispersive X-ray Spectroscopy (EDS) spectra of the mild steel showed that the composition of Carbon and Oxygen increased by 4% and 24.31%, respectively. The increase might probably be attributed to the presence of (CH2) in CH2OH group. The presence of cavities and pits in the Scanning Electronic Microscope (SEM) images of mild steel showed the damages on the mild steel by corrosion medium. The corrosion rate of mild steel in 1M HCl decreased with an increase in the concentration of the extracts for the different concentrations of extracts used, 100% bitter leaf extract (BLE) has the highest corrosion inhibitory efficiency; this was closely followed by 1:4 blends of bitter leaf extract (BLE) and banana extract (BNE). 100 % BNE extract has the lowest inhibitory efficiency for the different ratios of extracts concentration used. Bitter leaves extracts have better inhibitory efficiency than Banana stem extracts.

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References

  1. O. I. Sekunowo, S. I. Durowaye, and G. I. Lawal, Potentio-dynamic Corrosion Study of Mild Steel in Seawater and 1M HCl. NSE Technical Transaction, 2017;51(1): 85-91.
     Google Scholar
  2. L.L. Shreir, Corrosion, Metal/Environmental Reaction, Newnes-Butterworths, London, UK, 1976, vol. 1, pp 1-6.
     Google Scholar
  3. V.S. Sastri, Green Corrosion Inhibitors: Theory and Practice, First Edition. John Wiley & Sons, Inc. Published 2011 by John Wiley & Sons, Inc, 2011.
     Google Scholar
  4. P. Rostron and S. Kasshanna, Novel Synthesis of Vegetable Oil Derived Corrosion Inhibitors. International Journal of Corrosion, 2015;2015:1-6.
     Google Scholar
  5. A. Ostovari, S. M. Hoseinieh, M. Peikari, S. R. Shadizadeh and S. J Hashemi, Corrosion inhibition of mild steel in 1M HCL solution by henna extract: A comparative constituent (lawsone, Gallic acid α-D- Glucoseand Tannic acid). Journal of Corrosion Science, 2009:51(9):1935-1949.
     Google Scholar
  6. A. Rani and J. B. Bharathi, Green inhibitors for protection of metals and alloys. International Journal of corrosion, 2012;20: 12-15.
     Google Scholar
  7. K. S. Okiongbo and G. Ogobiri, Predicting Soil Corrosivity along a Pipeline route in the Niger Delta Basin Using Geoelectrical Method. Implication for Corrosion Control Engineering 5:237-244, 2013.
     Google Scholar
  8. N. O. Eddy, E. E. Ebenso and A. O Odiongenyi, Corrosion inhibitive properties and adsorption behaviour of ethanol extract of piper guinensis as a green corrosion inhibitor for mild steel in H2SO4. African Journal of Pure and Applied Chemistry, 2008;2(11):107-115.
     Google Scholar
  9. M. A. Ameer and A. M Fekry, Corrosion inhibition of mild steel by natural product compound. Progress in Organic Coatings, 2011;71: 343-349.
     Google Scholar
  10. I. C. Awe, A. S. Abdulrahaman, H. K. Ibrahim, A. G. Kareem and S. M. Adams, Inhibitive Performance of Bitter Leaf Root Extract on Mild Steel Corrosion in Sulphuric Acid Solution. American Journal of Materials Engineering and Technology, 2015;3(2): 35-45.
     Google Scholar
  11. J. H Doughari, Phytochemical: Extraction Methods, Basic Structures and Mode of Action as Potential Chemotherapeutic Agents, Phytochemical – A Global Perspective of Their Role in Nutrition and Health, 2012.
     Google Scholar
  12. T. J. Tuaweri, E. A. Ogbonnaya and O.O. Onyemaobi, Corrosion Inhibition of Heat Treated Mild Steel with Neem Leave Extract in a Chloride Medium. International Journal of Research in Engineering and Technology, 2015;4(6): 404-409.
     Google Scholar
  13. B. S. Prathibha, P. Kotteeswaran and V.B Raju, Study on the inhibition of mild steel corrosion by N, N-dimethyl-N-(2- phenoxyethyl)dodecan-1-aminiumbromide in HCl medium, IOSR Journal of Applied Chemistry media. Journal of chil. Chem. Soc., 2015;52:1206.
     Google Scholar
  14. G. E. Debi, H. Esah, I. Mohammed, A. S. Abdulrahman and M. Aminu, Effect of Vernonia Amygdalina Extract on Corrosion Inhibition of Mild Steel in Simulated seawater. Australian Journal of basic and Applied Sciences, 2013;7(14): 257-263.
     Google Scholar
  15. K .F. K. Oyedeko, M. O. Omidiji. .O Akinyemi and A. Adesina, Use of vernonia amygdalina (bitter leaf) for Corrosion Inhibition of Mild Steel in Sea Water, LASU Journal of Engineering, Science and Technology, 2019; 1(2).
     Google Scholar
  16. T. Seth, A. Chaturved, R. K. Updhyay and S. P. Mathur, Corrosion inhibitory effects of some schiffs bases on mild steel in acidic medium, 2007;52(3):1206-1213.
     Google Scholar
  17. G. N. Chukwueze and N.A.G. Aneke, Comparative analysis of corrosion inhibition of mild steel using pawpaw and Neem Leaves extracts in Sulphuric acid medium. International Journal of Novel Research in Physics Chemistry & Physics, 2019;6(3):7-13.
     Google Scholar
  18. O. O. Obiukwu, I. O. Opara and B. C. Oyinna, Corrosion Inhibition of Stainless Steel Using Plant Extract Vemonia amygdalina and Azadirachta indica. Pacific Journal of Science and Technology, 2013; 14(2): 31-35.
     Google Scholar